For Immediate Release
August 11, 1995
A BRIGHTER FUTURE FOR RECYCLED PAPER: TECHNOLOGY IMPROVES INK REMOVAL,
WORKS WITH EXISTING EQUIPMENT
Recycled paper has a brighter future thanks to a patented technology
for removing ink and laser printer toner from recycled fibers.
Researchers at the Georgia Institute of Technology are applying a direct
current electric field to recycled fiber slurry, removing more ink, reducing
chemical use and making the resulting fibers brighter than traditional
de-inking processes do. The Georgia Tech process is especially effective
for dirts (dark specks) reduction on laser-printed waste paper like that
produced in most offices, said Dr. Jeffery Hsieh, director of Pulp and
Paper Engineering.

Researchers use a laboratory-scale reactor to demonstrate
an improved process for de-inking recycled paper.
"The process can be applied to all kinds of paper -- lightweight coated
paper, newsprint and other kinds of fibers," said Hsieh, professor of
chemical engineering. "However, the most significant aspect of the process
is that it gets ink out of office waste by almost reversing the activity
of a laser printer."
In 1993, 8.4 million tons of printing and writing paper were recovered
for recycling, according to the American Forest and Paper Association.
The uniformity, availability and higher profits associated with this waste
stream put it in high demand for tissue paper, new printing and writing
paper, and exports. De-inking is one of the key operations performed in
recycling such paper.
However, much office paper has been laser printed. The heat used in laser
processing makes ink particularly hard to remove because it electronically
deposits ink particles on the fibers. Traditional recycling processes
rely on chemical and mechanical actions to remove ink from such fibers
and include several dispersion, flotation and washing steps. They reduce
fiber strength, which must be compensated for with the addition of fortifying
chemicals.
"These operations add to the cost of recycling and make it less economical,
compared to virgin paper-making," Hsieh explained. "There is a need for
technology that de-inks fibers in fewer stages, to reduce fiber destruction
and cost."
The de-inking process developed at Georgia Tech is based on a reactor
comprising a central anode and a perimetal cathode, which can be retrofitted
to existing recycled paper processing equipment.
Ink particles carry charges ranging from high positive to weak negative;
paper fibers usually carry a weak negative charge. Applying the direct
current field to a reactor full of fiber slurry attracts the ink particles
away from the fibers and causes the ink to coagulate. The massed particles
float to the surface of the slurry with some help from gas bubbles generated
by the electric field. The coagulated ink is then skimmed off the top
of the slurry using rotation scoops, continuous conveyors, or other means.
This process removes twice as many of the ink specks from office paper,
compared to traditional de-inking without the electric field. Paper made
from the treated fibers has a significantly lower number of ink specks
per recycled handsheet, when compared to a control sheet.
The electric current also helps to remove dust particles from the fiber
and creates oxygen in the reactor -- both actions improve fiber brightness
and whiteness. Brightness evaluations showed an increase of two to six
points on samples of paper ranging from newsprint offset printing.
Finally, test results of tear, tensile and burst show that the strength
of paper made from the Georgia Tech de-inked fibers is at least equal
to that of control sheets. This results from the use of fewer mechanical
steps and chemical additions that are known to weaken fibers.
If a reactor operator chose to use chemicals in the de-inking process,
smaller amounts could be used because the electric current dissociates
them through the reactor, increasing their efficiency, Hsieh says. The
operator also could turn off the de-inking cell if he did not want to
use the current on a particular batch of paper.
This process specifically addresses de-inking, while other patented electric
processes focus on different objectives. The patent was issued on August
24, 1993 and a presentation on the work appears in the 1992 AIChe Forest
Products Symposium Proceedings. Future research could address how the
charge affects the metallurgy of reactor shafts, Hsieh says, as well as
pilot plant trials and mill scale ups.
Hsieh is director of the Center for Excellence for High Yield Pulp Science
at Georgia Tech, and is an adjunct professor at the Institute of Paper
Science and Technology. He recently was named a Fellow of the Technical
Association of the Pulp and Paper Industry for his service the association
and the pulp and paper industry.
RESEARCH NEWS AND PUBLICATIONS OFFICE
Georgia Institute of Technology
75 Fifth Street, N.W., Suite 100
Atlanta, Georgia 30308
MEDIA RELATIONS CONTACTS:
John Toon (404-894-6986);
Internet: john.toon@edi.gatech.edu;
FAX: (404-894-4545)
TECHNICAL:
Dr. Jeffery Hsieh (404-894-3556);
Internet: jeffery.hsieh@che.gatech.edu
WRITER: Lea McLees
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